REN Lijie, MA Xiulan, BIAN Weitao, et al. The Adsorption Characteristic Research of Pb in Reservior Sediment[J]. 2016, 30(5): 255-260. DOI: 10.13870/j.cnki.stbcxb.2016.05.042.
In order to study the adsorption behavior of lead in sediment and soil
the adsorption of Pb adsorption in sediment and soil were investigated by batch equilibrium studies according to OECD guideline 106
and the influence of the pH
organic matter and N
P concentration on adsorption process were also discussed in this study. The results showed that the adsorption isotherm of Pb was well fitted with the Temkin equation in the soil
the correlation constant were 0.925; the adsorption isotherm of Pb was well fitted with the Freundlich equation in the soil
the correlation constant were 0.971. Study showed that
Pb under the adsorption condition of 15
25 and 35℃
with the increase of temperature
the adsorption of Pb in sediment and soil would be strengthened
ΔG<0
ΔH>0
revealed that the adsorption of Pb in the sediment and soil was a spontaneously endothermic process. Study showed that
under the pH condition of 3~11
the Pb adsorption quantity increased with the increase of pH
after the first increased and then to be gentled. When the pH was equal to 5
the adsorption effect was best. After removal of the organic matter the adsorption amount of Pb in sediment and soil decreased by 121.6
87.4 mg/kg
respectively. With the increase of N
P
the adsorption amount of Pb in sediment and soil decreased
which might be due to with the carrying of N
P
the K+ was added
and it had a competitive adsorption of Pb led to reducing adsorption capacity of Pb.