Distribution Pattern of Cadmium in the Profile of Shallow Fissure Soil and Its Influencing Factors in Karst Areas with High Geological Background

FAN Pingping; CHEN Jia; ZHANG Feng; NIU Yong; FANG Nufang; WU Zeyan; CAI Huayin

doi:10.13870/j.cnki.stbcxb.2024.06.033

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Distribution Pattern of Cadmium in the Profile of Shallow Fissure Soil and Its Influencing Factors in Karst Areas with High Geological Background

更新时间：2025-02-18

- Distribution Pattern of Cadmium in the Profile of Shallow Fissure Soil and Its Influencing Factors in Karst Areas with High Geological Background
- Vol. 38, Issue 6, Pages: 310-321(2024)
- 作者机构：
  
  1. 贵州大学农学院,贵阳,550025
  2. 自然资源部岩溶生态系统与石漠化治理重点实验室, 中国地质科学院岩溶地质研究所,广西,桂林,541004
  3. 广西平果喀斯特生态系统国家野外科学观测研究站,广西,桂林,541004
  4. 西北农林科技大学黄土高原土壤侵蚀与旱地农业国家重点实验室, 陕西杨凌,712100
- 作者简介：
- 基金信息：
- DOI：10.13870/j.cnki.stbcxb.2024.06.033
  CLC： X171.5
- Published：2024
- 稿件说明：
移动端阅览
FAN Pingping, CHEN Jia, ZHANG Feng, et al. Distribution Pattern of Cadmium in the Profile of Shallow Fissure Soil and Its Influencing Factors in Karst Areas with High Geological Background[J]. 2024, 38(6): 310-321.
DOI：

FAN Pingping, CHEN Jia, ZHANG Feng, et al. Distribution Pattern of Cadmium in the Profile of Shallow Fissure Soil and Its Influencing Factors in Karst Areas with High Geological Background[J]. 2024, 38(6): 310-321. DOI： 10.13870/j.cnki.stbcxb.2024.06.033.

摘要

[目的] 研究浅层喀斯特裂隙土壤Cd的剖面分布规律

分析不同因素对裂隙中Cd分布的影响状况

为今后研究地下裂隙土壤中Cd的分布规律及Cd污染防治提供科学依据。[方法] 以黔西北典型地质高背景区小流域为研究对象

系统分析浅层裂隙土壤Cd的全量和形态

以及pH、有机质含量、阳离子交换量(CEC)、粒径和团聚体等5种土壤性质指标

通过方差和相关分析阐明裂隙剖面土壤Cd的分布规律及其影响因子。[结果] (1)裂隙土壤的理化因子对Cd分布影响显著;(2)裂隙土壤pH平均为6.70

Cd含量平均为2.99 mg/kg

其剖面分布呈现0—20 cm富集

随土层深度增加逐渐减少

赋存形态以可还原态为主;(3)Cd全量主要受pH、CEC、黏粒、粉粒和水稳性团聚体的共同影响

但其剖面分布的主控因子是CEC;(4)Cd形态分布的控制因子则因形态而异

弱酸提取态的分布主要受有机质控制

可还原态主要受CEC控制

可氧化态受CEC、黏粒和粉粒共同影响

残渣态的主控因子为粉粒含量;(5)漏斗形和梯形裂隙剖面土壤Cd含量显著小于长方形裂隙剖面土壤Cd含量。[结论] 裂隙土壤Cd剖面分布规律受土壤理化性质和裂隙形态共同影响

长方形裂隙更易导致Cd的累积。

Abstract

[Objective] To study the vertical distribution pattern of cadmium (Cd) in shallow karst fissure soil

analyze the impacts of various factors on the distribution of Cd in fissures

and provide a scientific basis for future research on the distribution pattern of Cd in underground fissure soil and the prevention and control of Cd pollution. [Methods] Taking the small watershed of Baobao Mountain in Weining County

a region with a typical high geological background in the northwest of Guizhou

as the research object

the total Cd concentration and speciation of Cd in shallow fissure soil

along with five soil property indicators such as pH value

organic matter content

cation exchange capacity (CEC)

particle size

and aggregate were systematically analyzed. The distribution pattern of Cd and its influencing factors were examined using one-way ANOVA and correlation analysis. [Results] (1) The physical and chemical properties of the fissure soil significantly affected the distribution of Cd. (2) The average pH value of the fissure soil was 6.70. The average Cd concentration was 2.99 mg/kg

the concentration was high at 0—20 cm and gradually decreased with increasing soil depth

and Cd was predominantly in the reducible form. (3) Total Cd concentration was mainly influenced by soil pH

CEC

clay

silt

and water-stable aggregates

with CEC being the primary controlling factor for the vertical distribution of Cd. (4) The distribution of Cd speciation was controlled by different factors

depending on the form of Cd

with the weak acid-extractable form primarily influenced by organic matter

the reducible form mainly influenced by CEC

the oxidizable form mainly influenced by CEC

clay

and silt

and the residual form mainly influenced by silt content. (5) There was a significant difference in Cd concentration between the soils of funnel-shaped and trapezoidal fissure profiles and the rectangular fissure profile. [Conclusion] The vertical distribution pattern of Cd in fissure soil is jointly influenced by soil physicochemical properties and fissure morphology

with rectangular fissures being more conducive to the accumulation of Cd.

关键词

Keywords

references

赵其国,骆永明.论我国土壤保护宏观战略[J].中国科学院院刊,2015,30(4):452-458. ZHAO Q G, LUO Y M. The macro strategy of soil protection in China[J].Bulletin of Chinese Academy of Sciences, 2015,30(4):452-458.

全国土壤污染状况调查公报(2014年4月17日)[J].环境教育,2014(6):8-10. National Soil Contamination Survey Bulletin (April 17, 2014)[J].Environmental Education,2014(6):8-10.

张信宝,王世杰,曹建华,等.西南喀斯特山地水土流失特点及有关石漠化的几个科学问题[J].中国岩溶,2010,29(3):274-279. ZHANG X B, WANG S J, CAO J H, et al. Characteristics of water loss and soil erosion and some scientific problems on Karst rocky desertification in Southwest China Karst area[J].Carsologica Sinica,2010,29(3):274-279.

QIN W J, HAN D M, SONG X F, et al. Sources and migration of heavy metals in a Karst water system under the threats of an abandoned Pb-Zn Mine, Southwest China[J].Environmental Pollution,2021,277:e116774.

戴全厚,严友进.西南喀斯特石漠化与水土流失研究进展[J].水土保持学报,2018,32(2):1-10. DAI Q H, YAN Y J. Research progress of Karst rocky desertification and soil erosion in southwest China[J]. Journal of Soil and Water Conservation,2018,32(2):1-10.

雷俐,魏兴琥,徐喜珍,等.粤北岩溶山地土壤垂直渗漏与粒度变化特征[J].地理研究,2013,32(12):2204-2214. LEI L, WEI X H, XU X Z, et al. Vertical distribution of migration channels and grain-size change features of soil in Karst mountainous areas of northern Guangdong[J].Geographical Research, 2013,32(12):2204-2214.

朱舒,李舒怡,鱼洋,等.关中平原农田土壤剖面重金属空间分布、影响因素、风险评价及源解析.环境科学,2024,https://doi.org/10.13227/j.hjkx.202403016. ZHU S, LI S Y, YU Y, et al. Spatial distribution, influencing factors, risk assessment and source analysis of heavy metals in soil profile of farmland on the Guanzhong Plain.Environmental Science,2024,https://doi.org/10.13227/j.hjkx.202403016.

王雪雯,刘鸿雁,顾小凤,等.地质高背景与污染叠加区不同土地利用方式下土壤重金属分布特征[J].环境科学,2022,43(4):2094-2103. WANG X W, LIU H Y, GU X F, et al. Distribution characteristics of heavy metals in soils affected by different land use types in a superimposed pollution area with high geological background[J].Environmental Science,2022,43(4):2094-2103.

罗谦,李英菊,秦樊鑫,等.铅锌矿区周边耕地土壤团聚体重金属污染状况及风险评估[J].生态环境学报,2020,29(3):605-614. LUO Q, LI Y G, QIN F X, et al. Contamination status and risk assessment of heavy metals in soil aggregates of Pb-Zn mining area[J].Ecology and Environmental Sciences,2020,29(3):605-614.

彭旭东.喀斯特高原坡地浅层孔(裂)隙水土漏失过程及特征研究[D].贵阳:贵州大学,2019. PENG X D. Study on the process and characteristics of water & soil leakage loss in shallow fissures on sloping lands of Karst Plateau[D].Guiyang: Guizhou University,2019.

YAN Y J, DAI Q H, YANG Y Q, et al. Effects of vegetation restoration types on soil erosion reduction of a shallow Karst fissure soil system in the degraded Karst areas of Southwestern China[J]. Land Degradation and Development, 2023,34(8):2241-2255.

FANG T, YANG K, LU W X, et al. An overview of heavy metal pollution in Chaohu Lake, China: Enrichment, distribution, speciation, and associated risk under natural and anthropogenic changes[J].Environmental Science and Pollution Research,2019,26(29):29585-29596.

王艺惠,文鑫,钟聪,等.桂西北岩溶地质高背景和矿业活动叠加区土壤剖面镉分布特征及生物有效性[J].地球科学与环境学报,2024,46(1):81-95. WANG Y H, WEN X, ZHONG C, et al. Distribution characteristics and bioavailability of cadmium in soil profile from Karst high geological background and mining activities superimposed pollution area of northwest Guangxi, China[J].Journal of Earth Sciences and Environment,2024,46(1):81-95.

李焱秋,戴全厚,任青青,等.喀斯特浅层裂隙土壤垂向渗透性及影响因素[J].水土保持学报,2020,34(3):150-155. LI Y Q, DAI Q H, REN Q Q, et al. Vertical permeability of Karst shallow fissure and its influencing factors[J].Journal of Soil and Water Conservation,2020,34(3):150-155.

熊佰炼,高扬,彭韬,等.喀斯特坡地浅层岩溶裂隙土壤团聚体稳定性与养分垂向变化特征[J].土壤学报,2021,58(6):1472-1485. XIONG B L, GAO Y, PENG T, et al. Characteristics of vertical variation of soil aggregates stability and nutrients in shallow Karst fissures of Karst sloping fields[J].Acta Pedologica Sinica, 2021,58(6):1472-1485.

陈文轩,李茜,王珍,等.中国农田土壤重金属空间分布特征及污染评价[J].环境科学,2020,41(6):2822-2833. CHEN W X, LI X, WANG Z, et al. Spatial distribution characteristics and pollution evaluation of heavy metals in arable land soil of China[J].Environmental Science,2020,41(6):2822-2833.

刘南婷,刘鸿雁,吴攀,等.典型喀斯特地区土壤重金属累积特征及环境风险评价[J].农业资源与环境学报,2021,38(5):797-809. LIU N T, LIU H Y, WU P, et al. Accumulation characteristics and environmental risk assessment of heavy metals in typical Karst soils[J].Journal of Agricultural Resources and Environment,2021,38(5):797-809.

罗舒玉,邓羽松,陈洪松,等.干湿交替条件下喀斯特峰丛洼地土壤裂隙发育规律[J].应用生态学报,2023,34(2):387-395. LUO S Y, DENG Y S, CHEN H S, et al. Development law of soil cracks in Karst peak-cluster depressions under dry and wet alternations[J].Chinese Journal of Applied Ecology,2023,34(2):387-395.

中华人民共和国环境保护部.固体废物金属元素的测定电感耦合等离子体质谱法: HJ 766—2015[S].北京:中国环境科学出版社,2015. Ministry of Ecology and Environment. HJ 766—2015 Solid Waste—Determination ofmetals—Inductively coupled plasma massspectrometry (ICP-MS)[S].China Environmental Science Press,2015.

罗慧,刘秀明,王世杰,等.中国南方喀斯特集中分布区土壤Cd污染特征及来源[J].生态学杂志,2018,37(5):1538-1544. LUO H, LIU X M, WANG S J, et al. Pollution characteristics and sources of cadmium in soils of the Karst area in South China[J].Chinese Journal of Ecology,2018,37(5):1538-1544.

刘方,王金凤,朱健,等.地质条件制约对喀斯特区域土壤Cd累积及空间分布的影响[J].贵州大学学报(自然科学版),2021,38(3):10-16. LIU F, WANG J F, ZHU J, et al. The influence of geological conditions on accumulation and spatial distribution of soil Cd in Karst area[J].Journal of Guizhou University (Natural Sciences),2021,38(3):10-16.

米雅竹,梁家妮,周俊,等.典型冶炼厂大气沉降区农田耕层土壤重金属(Cd、Cu、Pb)输入输出平衡研究[J].土壤学报,2024,61(5):1339-1348. MI Y Z, LIANG J N, ZHOU J,et al. Input and Output Balance of Heavy Metals(Cd, Cu, Pb) in Arable Soils in Atmospheric Deposition Area of Typical Smelter[J].Acta Pedologica Sinica,2024,61(5):1339-1348.

WU J Z, LI Z T, HUANG D, et al. A novel calcium-based magnetic biochar is effective in stabilization of arsenic and cadmium co-contamination in aerobic soils[J].Journal of Hazardous Materials,2020,387:e122010.

梅雪,刘鸿雁,吴龙华,等.基于HDXRF和ICP-MS的黔西北土壤重金属空间分布及影响因素研究[J].土壤,2023,55(2):399-408. MEI X, LIU H Y, WU L H,et al. Spatial Distribution of Soil Heavy Metal Contents and Influencing Factors in Northwest of Guizhou Based on HDXRF and ICP-MS[J].Soils,2023,55(2):399-408.

王文栋,任振武,张红英,等.新疆天山中部森林土壤重金属含量及其与土壤理化性质的相关性[J].西北农林科技大学学报(自然科学版),2021,49(3):47-56. WANG W D, REN Z W, ZHANG H Y,et al. Soil heavy metal contents and correlations with soil physical and chemical properties in central Tianshan forest, Xinjiang[J].Journal of Northwest A&F University(Natural Science Edition),2021,49(3):47-56.

LUO G F, HAN Z W, XIONG J, et al. Heavy metal pollution and ecological risk assessment of tailings in the Qinglong Dachang antimony mine, China[J].Environmental Science and Pollution Research,2021,28(25):33491-33504.

HUANG B, YUAN Z J, LI D Q, et al. Effects of soil particle size on the adsorption, distribution, and migration behaviors of heavy metal(loid)s in soil: A review[J].Environmental Science Processes & Impacts,2020,22(8):1596-1615.

LI Y L, DONG S F, QIAO J C, et al. Impact of nanominerals on the migration and distribution of cadmium on soil aggregates[J].Journal of Cleaner Production,2020,262:e121355.

强瑀,李英菊,罗谦,等.典型铅锌矿区耕地土壤团聚体重金属含量与农作物含量相关性及其风险评价[J].环境科学,2021,42(12):5967-5976. QIANG Y, LI Y J, LUO Q, et al. Relationship characteristics and risk assessment of heavy metal contents in soil aggregates and in crops around a typical Pb-Zn mining area[J].Environmental Science, 2021,42(12):5967-5976.

王娟恒,温汉辉,蔡立梅,等.广东揭阳土壤镉含量的空间分布特征及影响因素[J].现代地质,2020,34.(1):88-96. WANG J H, WEN H H, CAI L M,et al. Spatial Distribution Characteristics and Influencing Factors of Soil Cadmium Content in Jieyang of Guangdong Province[J].Geoscience,2020,34.(1):88-96.

李颢,陈敬龙,段华泰,等.工业和农业污染稻田土壤重金属的赋存形态及水稻吸收运移比较[J].土壤通报,2022,53(1):204-212. LI H, CHEN J L, DUAN H T, et al. Comparison of the forms of heavy metals and the absorption and transport by rice between industrial and agricultural contaminated paddy soils[J].Chinese Journal of Soil Science,2022,53(1):204-212.

朱煊,马红艳,石秀顶,等.电动修复对土壤铅形态及伴矿景天铅富集的影响[J].土壤通报,2024,55(3):852-861. ZHU X, MA H Y, SHI X D, et al. Effect of electrokinetic remediation on lead form in soil and the enrichment of sedum plumbizincicola[J].Chinese Journal of Soil Science,2024,55(3):852-861.

凌云,刘汉燚,张小婷,等.西南地区典型土壤酸化特征及其与重金属形态活性的耦合关系[J].环境科学,2023,44(1):376-386. LING Y, LIU H Y, ZHANG X T, et al. Characteristics of typical soil acidification and effects of heavy metal speciation and availability in southwest China[J].Environmental Science, 2023,44(1):376-386.

赵茹,邵国胜,胡钧铭,等.南方喀斯特矿区稻田土壤镉污染的原位营养修复效果研究[J].中国农学通报,2024,40(23):75-80. ZHAO R, SHAO G S, HU J M, et al. Preliminary study on effect of cadmium contaminated in paddy fields of Karst mining area

In-situ

remediation[J].Chinese Agricultural Science Bulletin,2024,40(23):75-80.

唐婵.生物炭基复合钝化材料对镉污染土壤的钝化效应[D].成都:四川农业大学,2020. TANG C. The immobilization effect of biochar-basedcompound amendment materials on Cdcontaminated soils[D].Chengdu: Sichuan Agricultural University,2020.

潘泳兴,陈盟,王櫹橦.典型铅锌矿流域土壤重金属累积与分布的影响因素分析[J].环境科学,2023,44(11):6071-6084. PAN Y X, CHEN M, WANG X T. Analysis of influencing factors on the accumulation and distribution of heavy metals in soil of a typical lead-zinc mine watershed[J].Environmental Science,2023,44(11):6071-6084.

陈佳,范萍萍,龙文涛,等.土壤侵蚀对重金属迁移的作用规律与机制研究进展[J].水土保持研究,2024,31(1):460-470. CHEN J, FAN P P, LONG W T, et al. Research progress in mechanism of impact of soil erosion on heavy metal migration[J].Research of Soil and Water Conservation,2024,31(1):460-470.

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