Differential Adsorption of Nitrate Nitrogen and Ammonium Nitrogen in Water by Carbonized Apple Bark and Wood

SHI Junyuan; XUN Mi; CUI Yingbin; LU Lei; WANG Zepeng; ZHANG Weiwei; YANG Hongqiang

doi:10.13870/j.cnki.stbcxb.2020.02.036

您当前的位置：

首页 >

文章列表页 >

Differential Adsorption of Nitrate Nitrogen and Ammonium Nitrogen in Water by Carbonized Apple Bark and Wood

更新时间：2025-03-12

- Differential Adsorption of Nitrate Nitrogen and Ammonium Nitrogen in Water by Carbonized Apple Bark and Wood
- Vol. 34, Issue 2, Pages: 253-260(2020)
- 作者机构：
  
  山东农业大学园艺科学与工程学院, 作物生物学国家重点实验室,山东,泰安,271018
- 作者简介：
- 基金信息：
- DOI：10.13870/j.cnki.stbcxb.2020.02.036
  CLC： X52
- Published：2020
- 稿件说明：
移动端阅览
SHI Junyuan, XUN Mi, CUI Yingbin, et al. Differential Adsorption of Nitrate Nitrogen and Ammonium Nitrogen in Water by Carbonized Apple Bark and Wood[J]. 2020, 34(2): 253-260.
DOI：

SHI Junyuan, XUN Mi, CUI Yingbin, et al. Differential Adsorption of Nitrate Nitrogen and Ammonium Nitrogen in Water by Carbonized Apple Bark and Wood[J]. 2020, 34(2): 253-260. DOI： 10.13870/j.cnki.stbcxb.2020.02.036.

摘要

将苹果枝条的皮层和木材部分开后在450℃下低氧加热制得炭化枝皮和炭化木材，分析其超微结构及对铵态氮和硝态氮的吸附。结果表明，苹果枝皮比其木材部分的纤维素含量高，有更多的微观孔洞和沟壑，炭化后纵向沟壑和孔隙更发达。炭化枝皮对NH4+—N和NO3-—N的饱和吸附量分别为24.11，12.93 mg/g，炭化木材的相应参数分别为22.24，11.99 mg/g，炭化枝皮对NH4+—N和NO3-—N的吸附能力均比炭化木材的更强。两者对NH4+—N的吸附量比对NO3-—N的更大，吸附过程均能采用Freundlich和Langmuir等温吸附模型、准二级动力学模型和Elovich模型拟合。炭化枝皮的吸附能力比炭化木材更强，与其原料纤维素含量高及微观沟壑发达有关。

Abstract

The bark and wood of the apple branches were separated and then made them into carbonized bark and wood in low oxygen at 450℃.The ultrastructural and adsorption to NH4+-N and NO3--N of them were investigated. The results showed that the cellulose content in carbonized bark was higher than that in carbonized wood

and there were more microscopic holes and gullies in the carbonized bark

and the longitudinal gullies and pores were more developed after carbonization. The saturated adsorption capacity of the carbonized bark to NH4+-N and NO3--N was 24.11 mg/g and 12.93 mg/g

respectively; while the corresponding parameter of the carbonized wood was 22.24 mg/g and 11.99 mg/g

respectively

and carbonized bark had stronger adsorption capacity to NH4+-N and NO3--N than that of carbonized wood. The adsorption capacities of these two kinds of materials to NH4+-N were greater than those to NO3--N. Freundlich and Langmuir isothermal adsorption models

pseudo second-order kinetic model and Elovich model could be used to fit the adsorption processes. Carbonized bark had stronger adsorption capacity

which was related to its higher cellulose content and more developed microscopic gullies.

关键词

Keywords

references

Zhang X X, Yin S, Li Y S, et al. Comparison of greenhouse gas emissions from rice paddy fields under different nitrogen fertilization loads in Chongming Island, Eastern China[J].Science of the Total Environment,2014,472:381-388.

Guo J H, Liu X J, Zhang Y, et al. Significant acidification in major Chinese croplands[J].Science,2010,327(5968):1008-1010.

Jin X C, Xu Q J, Hang C Z. Current status and future tendency of lake eutrophication in China[J].Science in China (Series C:Life Sciences),2005,48(S2):948-954.

Weber K, Quicker P. Properties of biochar[J].Fuel,2018,217:240-261.

武丽君,王朝旭,张峰,等.玉米秸秆和玉米芯生物炭对水溶液中无机氮的吸附性能[J].中国环境科学,2016,36(1):74-81.

宋婷婷,赖欣,王知文,等.不同原料生物炭对铵态氮的吸附性能研究[J].农业环境科学学报,2018,37(3):576-584.

闫丽娟,杨洪强,苏倩,等.施用炭化苹果枝粉末对平邑甜茶生长及根系构型的影响[J].园艺学报,2014,41(7):1436-1442.

曹辉,李燕歌,周春然,等.炭化苹果枝对苹果根区土壤细菌和真菌多样性的影响[J].中国农业科学,2016,49(17):3413-3424.

Cao H, Feng F, Xun M, et al. Effect of carbonized apple wood on nitrogen-transforming microorganisms and nitrogen oxides in soil of apple tree root zone[J].European Journal of Soil Science,2018,69(3):545-554.

Cao H,Ning L F,Xun M, et al. Biochar can increase nitrogen use efficiency of Malus hupehensis by modulating nitrate reduction of soil and root[J].Applied Soil Ecology,2019,135:25-32.

波钦诺克,荆家海,丁钟荣.植物生物化学分析方法[M].北京:科学出版社,1981.

熊素敏,左秀凤,朱永义.稻壳中纤维素、半纤维素和木质素的测定[J].粮食与饲料工业,2005(8):40-41.

Nocentini C, Certini G, Knicker H, et al. Nature and reactivity of charcoal produced and added to soil during wildfire are particle-size dependent[J].Organic Geochemistry,2010,41(7):682-689.

Calvelo Pereira R, Kaal J, Camps Arbestain M, et al. Contribution to characterisation of biochar to estimate the labile fraction of carbon[J].Organic Geochemistry,2012,42(11):1331-1342.

Uchimiya M, Hiradate S, Antal M J. Influence of carbonization methods on the aromaticity of pyrogenic dissolved organic carbon[J].Energy and Fuels,2015,29(4):2503-2513.

Essandoh M, Wolgemuth D, Jr C U P, et al. Adsorption of metribuzin from aqueous solution using magnetic and nonmagnetic sustainable low-cost biochar adsorbents[J].Environmental Science and Pollution Research,2017,24(5):4577-4590.

鲍士旦.主壤农化分析[M].北京:中国农业出版社,2000.

宋歌,孙波,教剑英.测定土壤硝态氮的紫外分光光度法与其他方法的比较[J].土壤学报,2007,44(2):288-293.

Yang H P, Yan R, Chen H P, et al. Characteristics of hemicellulose, cellulose and lignin pyrolysis[J].Fuel,2007,86(12/13):1781-1788.

索桂芳,吕豪豪,汪玉瑛,等.不同生物炭对氮的吸附性能[J].农业环境科学学报,2018,37(6):1193-1202.

邢英,李心清,周志红,等.生物炭对水体中铵氮的吸附特征及其动力学研究[J].地球与环境,2011,39(4):511-516.

邵云,陈静雯,王温澎,等.四种有机物料对Pb

的吸附特性[J].农业环境科学学报,2017,36(9):1858-1867.

王荣荣,赖欣,李洁,等.花生壳生物炭对硝态氮的吸附机制研究[J].农业环境科学学报,2016,35(9):1727-1734.

颜钰,王子莹,金洁,等.不同生物质来源和热解温度条件下制备的生物炭对菲的吸附行为[J].农业环境科学学报,2014,33(9):1810-1816.

李美璇,王观竹,郭平.生物炭对冻融黑土中铵态氮和硝态氮淋失的影响[J].农业环境科学学报,2016,35(7):1360-1367.

王彤彤,马江波,曲东,等.两种木材生物炭对铜离子的吸附特性及其机制[J].环境科学,2017,38(5):2161-2171.

Abdel-Fattah T M, Mahmoud M E, Ahmed S B, et al. Biochar from woody biomass for removing metal contaminants and carbon sequestration[J].Journal of Industrial and Engineering Chemistry,2015,22:103-109.

Lu H L, Zhang W H, Yang Y X, et al. Relative distribution of Pb

sorption mechanisms by sludge-derived biochar[J].Water Research,2012,46(3):854-862.

Bock E, Smith N, Rogers M, et al. Enhanced nitrate and phosphate removal in a denitrifying bioreactor with biochar[J].Journal of Environment Quality,2015,44(2):605-613.

Chintala R, Mollinedo J, Schumacher T E, et al. Nitrate sorption and desorption in biochars from fast pyrolysis[J].Microporous and Mesoporous Materials,2013,179:250-257.

Wang X H, Song R H, Yang H C, et al. Fluoride adsorption on carboxylated aerobic granules containing Ce(III)[J].Bioresource Technology,2013,127:106-111.

Views

1024

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Distribution Characteristics of Aggregates in Granitic Sandy Soil and Eel Clayey Soil and Their Effects on Cadmium Adsorption and Speciation

Adsorbing Properties of Brown Soil to Copper

N Variation in Rice-Soil-Water System Under Different N Application Level in High-yielding Paddy Field and Its Environment Effect

Preliminary Study on Variation Feature of Grassland Soil Organic Matter and Nitrogen in Western Karst Rocky Desertification Region, Guizhou Province

Effect of Nitrogen Fertilizer on Soil Enzymatic Activity and Rhizosphere Microorganisms of Wheat

Related Author

HE Rujing

LONG Jian

FAN Haijin

XIAO Ziman

ZHANG Kun

HOU Yingshan

HOU Hongbo

PENG Peiqin

Related Institution

Hunan Engineering Laboratory for Rice Quality and Safety Control

College of Environmental Science and Engineering， Central South University of Forestry and Technology

NING Jian-feng,XU Pei-zhi,YANG Shao-hai,ZOU Xian-zhong,LUO Wen-jian,CHEN Yong,SUN Li-li,WEI Lan,WU Jin-long(Soil and Fertilizer Institute,Guangdong Academy of Agricultural Sciences,Guangdong Key Laboratory of Nutrient Cycling and Farmland Conservation,,)

WANG Shuang,ZHAO Lan-po (College of Resources and Environment,Jilin Agricultural University,)

北京市农林科学院植物营养与资源研究所,北京,1000972. 北京市农林科学院植物营养与资源研究所,北京,1000973. 南京大学地理与海洋科学学院

⁰